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The lindane legacy

A meeting took place recently in Bilbao in the Basque country, Spain, where lindane production plants left 33 severely contaminated sites and over 5,000 tonnes of hexachlorocyclohexane (HCH) to be disposed of. Scientists, engineers and policy makers from 24 countries gathered for the 5th HCH and Pesticides Forum to learn and discuss disposal and management techniques. Mark Davis reports.

Protesters outside the 5th HCH and Pesticides Forum meeting campaigning against lindane

Outside the conference local campaigners wearing skeleton masks and acting out death from chemical releases protested about the authority's choice of methods for dealing with the waste chemicals and contaminated soil.
    HCH is a chemical cocktail of several isomers (variations on the chemical structure) which have been used for many years as insecticides. The most widely used, and the only one still in widespread use, is the gamma-HCH isomer which is also commonly known as lindane. The alpha, beta and delta isomers have largely been banned and are not intentionally manufactured, although in producing gamma-HCH small amounts of the other isomers are always produced.

The safety cell
Bilbao hosted two HCH production companies which operated between 1947-87.  After their closure 77,000 tonnes of contaminated soil and chemicals in 33 uncontrolled dumps, as well as 5,000 tonnes of pure HCH were left for the authorities to deal with.
    The method chosen for the uncontrolled dumps was to construct a sealed 'safety cell' at Bilbao Airport to which their contents would be transferred. The cell consists of several layers of under-seal and over-seal, leachate collection and processing and a landscaped surface. 113,000 m³ of contaminated soil were transferred and have now been sealed in the cell. 
    Local campaign group Herri Batasuna complains that the project has no adequate environmental impact assessment, there has been insufficient public consultation and no public agreement, and that the site is at risk from aircraft crashes and there is no emergency plan in place to deal with such an incident. The organisation is also unhappy about the planned Brakaldo safety cell which will contain additional 300,000 m³ of contaminated soil from 13 uncontrolled dumps.
    Vice Minister of the Environment for the Basque government, Esther Larrañaga said that after years of debate and inaction, decisions had to be taken. Any decision would have its critics, but they believed that the controlled landfill option and the sites chosen were the most appropriate.

HCH recycling
While the safety cells provide a solution for the uncontrolled dumps and contaminated soil, a different and equally controversial solution has been developed for the 5,000 tonnes of pure HCH left by Bilbao Chemical. Rather than burying or destroying the chemicals, the authorities have chosen to commission a plant to recycle it.
    On the site of a former HCH manufacturing plant, close to residential buildings and main roads, a plant is being constructed for the specific purpose of turning 5,000 tonnes of HCH into trichloro-benzene which has a commercial value as an intermediate in the manufacture of other chemical products. Once the reprocessing is complete the plant will be dismantled and sold. The buildings will be demolished, and together with the contaminated soil on which they stand will be landfilled in one of the safety cells.
    The process may be as safe as its enthusiastic implementers claim, or as risky as the protesters declare, but one wonders at the wisdom of locating such a facility in an urban environment, and whether the effort and expense of developing and constructing the plant can be justified.

5th HCH Pesticides Forum
The Basque country has a legacy of highly toxic waste to deal with. And they are not alone, as the HCH and Pesticides Forum heard. Poland has an estimated 60,000 tonnes of obsolete pesticides many of which are leaking into the soil and ground water from corroding concrete storage bunkers. The Netherlands has between  200,000-400,000 contaminated sites which will cost up to US$50 billion to clean up. In fact it is estimated that there is one polluted site for every 30-50 inhabitants in the industrialised countries.
    A large and highly technical industry is evolving rapidly to provide solutions to these problems. The techniques on offer include secure landfill, incineration, bioremediation, chemical and physical soil treatment and some novel experimental techniques.
    The box (below) describes the benefits and drawbacks to these technologies. The materials used to seal landfill sites may deteriorate with time allowing the contaminants to leak into the surrounding soil and water; incineration may create and release highly toxic dioxins and furans or other pollutants; bioremediation is too slow and specific, and soil washing does not completely clean the soil.
    Equally important are the questions of who pays for the clean-up and how can similar problems be prevented in the future? To its credit, the 5th HCH and Pesticides Forum addressed prevention by inviting Chiquita bananas to present their Integrated Production Management system in Costa Rica, Brazil to present its replacement and reduction of pesticide use in disease vector control, and the European Commission to present its Progressive Pest Management strategy developed by the Pesticides Trust [now PAN UK].
    The next Forum meeting will be held in Poland in the year 2000. As problems are being solved in the North will we continue to see similar problems of contamination and toxic waste expanding in the South? The future must look rosy for toxic waste handling and site decontamination contractors. (MD)

Disposal options

Dedicated incinerators
Dedicated toxic waste incinerators generally consist of a rotating furnace (rotary kiln) into which almost any kind of waste material including solids, liquids, steel drums and even BSE infected cows can be loaded. The waste is incinerated with the help of oil or some other fuel at temperatures above 1000oC and commonly in the range of 1200-1400oC. Exposure to these high temperatures converts the chemicals to gases which then enter an after burner to ensure their complete decomposition. The remaining compounds then pass into the  emission control equipment.
    Sophisticated emission control equipment is designed to limit stack emissions of potential contaminants to levels well within the most stringent limits and often below the limits of detection. This equipment generally includes quenchers, (which prevent the formation of dioxins and furans), electrostatic filters (which trap fine dust particles), acid washes (to neutralise alkaline emissions such as nitrogen oxides [NOx]), alkaline washes (to trap acid emissions such as sulphur oxides [SOx] and hydrochloric acid [HCl]) and active carbon filters (which trap rogue hydrocarbons and other potential contaminants).

Cement kilns
Cement kilns are primarily designed to burn limestone at temperatures between 1400-2000oC and are generally fuelled by fossil fuel. Their use to destroy toxic chemicals entails co-fuelling the kiln with fossil fuels and an appropriate mix of waste chemicals, depending on their properties. There are various designs of cement kilns but modern ones often consist of long rotary kilns which are not dissimilar to dedicated toxic waste incinerators except that their operating temperature is higher and the residence time of fuel and material at these high temperatures is often longer than in dedicated incinerators. Unlike dedicated incinerators cement kilns produce no toxic ash which requires disposal, but they tend to have less sophisticated emission control equipment and cannot accept materials for incineration which may contaminate or alter the properties of the cement being produced.
    There are reservations about cement kilns, but there is also interest in monitoring of progress.

Soil decontamination
Burning relatively clean chemicals is one matter, but dealing with contaminated materials such as soil is another matter altogether. The volumes of material are much greater, and soil particles, steel drums and many other materials do not burn. The two main options seem to be to separate the toxics from the other material and then treat the extracted toxics. The second option is to try to degrade the chemicals into benign or treatable components in situ.
    Separation can be achieved by various  methods. Some companies use thermal de-sorption which heats the soil to about 600oC causing the contaminants to evaporate, these are then passed to an after burner where they are conventionally incinerated. 
    Solvent extraction can be used to dissolve and extract the contaminants from the soil or other medium in which they are held. The solvents can be reused while chemicals are destroyed or safely contained.

Bioremediation
Certain microorganisms are able to digest some toxic chemicals and this is often an important route by which pesticides are degraded once applied in the field. By selecting the most effective microorganisms and creating ideal environmental conditions for them, It is sometimes possible to accelerate the degradation process significantly.  
    Bioremediation is being investigated as a way of decontaminating soils rather than destroying stocks of chemicals. It is a relatively undeveloped technology which currently seems limited to few chemicals and specific conditions. It is an area which will benefit from further research to develop widely applicable systems to assist in site decontamination.

 [This article first appeared in Pesticides News No. 41, September 1998, pages 6-7]


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