POPs contaminate Arctic polar bears

A new intergovernmental study of pollution in the Arctic has reported on concerns about levels of many persistent organic pollutant contaminants, and recommends that emission controls are an essential prerequisite to reduce exposure to humans and to protect wildlife.
    The Arctic Monitoring and Assessment Programme (AMAP) was established in 1991 by the ministers of the eight Arctic countries and charged with preparing an assessment of the state of the Arctic environment with respect to defined pollution issues. Accordingly, between 1991 and 1996 AMAP designed and implemented a monitoring programme and conducted its first assessment. About 400 projects delivered data to AMAP for consideration.

    The ensuing report, of mammoth size, comprises fully referenced, comprehensive, technical and scientifically presented assessments of the available and validated data. Even with this amount of information scientists contributing to the report are still concerned that there are too many gaps in our understanding of the pollution threats to the fragile Arctic ecosystem.
    The persistent organic pollutants (POPs) group of chemicals are identified as the primary concern. Pesticide and pesticide-contaminant POPs included in the study were aldrin, dieldrin, chlordane, DDT, hexachlorbenzene, technical HCH [a mixture of alpha, beta and gamma and delta hexachlorocyclohexanes], toxaphene, endosulfan, and tributyltin. All POPs considered by the AMAP monitoring programme have been found in air, snow, water, and/or wildlife in the Arctic.
    Monitoring of air in the Arctic has shown that levels of lindane (gamma HCH) and chlordane are correlated with long-range transport from usage in the mid-latitudes of North America, Europe and Asia. The highest levels of alpha HCH in the world's oceans are found in the Canada Basin and Canadian Arctic Archipelago. Exceptionally high HCH levels are found in Russian river water, especially the Ob (in north, central Russia). Ratios of gamma-HCH to alpha HCH indicate use of lindane.
    The infamous DDT is still widespread in the Arctic environment. Despite being widely restricted in some countries, DDT is still used for public health mosquito control in many tropical countries. The data for levels of DDT in Russian rivers, while reflecting some analytical quality assurance problems, show extraordinarily high residue levels when compared with urban areas of North America and western Europe. Levels of DDE, a breakdown product of DDT, in the Canadian population of tundra peregrine falcons, are still considered high enough to cause egg shell thinning.
    High levels of toxaphene were reported in fish higher up in the Arctic food chain. Toxaphene, another POP-used as an insecticide in Caribbean cotton production-has been found in Greenland halibut at levels that may be high enough to affect fry bone development and increase mortality during spawning. An extra concern is that very little information is available on the general toxicity of this chemical in animals.
    The anti-fouling paint, tributyltin, is probably causing imposex (see also p.16) in Arctic invertebrates in some harbours.
    Overall, the report concludes it is unlikely that levels of these POPs are declining in the Arctic environment. And it is not just older or defunct products that are of concern. The production and use of new organic chemicals, including new generation pesticides, are identified as potential threats.
    In some cases, a number of Arctic species have high enough POP levels to cause adverse effects. Therefore the report recommends:

AMAP Assessment Report: Arctic Pollution Issues, AMAP Secretariat, PO Box 8100, N-0032, Oslo, Norway, 1998, 859pp.

[This article first appeared in Pesticides News No. 42, December 1998, page 18]